Prepare the Pork Chops: Pat the pork chops dry with a paper towel to remove excess moisture. In a small bowl, mix salt, black pepper, garlic powder, and smoked paprika. Rub this seasoning mix evenly over both sides of the pork chops.
Preheat the Skillet: Heat a cast-iron skillet over medium-high heat and add olive oil.
Sear the Pork Chops: Place the pork chops in the hot skillet and sear for 3-4 minutes on one side, until a golden-brown crust forms.
Flip and Cook: Flip the pork chops and add butter, minced garlic, and thyme to the skillet. Cook for another 3-4 minutes, occasionally spooning the melted butter over the chops.
Check Temperature: Use a meat thermometer to check for doneness. The internal temperature should reach 140°F (60°C) for juicy, slightly pink pork chops. If needed, cook for an additional 1-2 minutes.
Rest and Serve: Remove the pork chops from the skillet and let them rest on a plate for 5 minutes. This allows the juices to redistribute. Serve warm with your favorite side dishes.